Natural Herbicides: Are they effective?

Jan 3, 2012

The public's increasing demand for safe “green” products has resulted in many new environmentally-friendly products becoming available for controlling weeds in the garden and landscape. Even though information for home gardeners on the efficacy of these new products is limited, their use is still heavily promoted by environmental awareness groups and public agencies in an effort to reduce the use of other herbicides that have a greater potential to contaminate surface waters. Retailers are beginning to dedicate shelf space to pesticides that are considered least-toxic alternatives; most of them containing essential oils or other natural plant extracts targeting weeds.

The majority of these “green” weed-control products are botanically based oils (e.g., clove oil, eugenol, and d-limonene), soaps (e.g., pelargonic acid), or acetic acid that control weeds by destroying the leaf cuticle or causing cell leakage that rapidly leads to death. Unfortunately, because these herbicides kill only green parts of the plant they contact, they don't provide long-term control of weeds with extensive root systems or underground storage structures such as rhizomes, tubers, or bulbs. Thus many treated plants are able to recover. In contrast, some conventional herbicides such as glyphosate or 2,4-D are translocated to roots or underground storage structures to kill larger plants and perennial weeds.

These types of herbicides are applied after the weeds have emerged (postemergent) and have little or no soil residual activity. They don't control weed seedlings that germinate after application. They kill the plants by breaking down plant membranes and are considered contact or burndown herbicides. These herbicides are very fast acting (Figure 1), but to be most effective they must contact all or most of the aboveground plant tissue. It is especially important to spray the growing points, or else the plant will regrow. Grasses and perennial weeds are difficult to control for an extended period of time, because they have some or all of their growing points below ground.

Figure 1. Effect of Bioganic herbicide on grass growth 1, 2, 14, 24, and 72 hours after application. However, the grass recovered in about 2 weeks.
Figure 1. Effect of Bioganic herbicide on grass growth 1, 2, 14, 24, and 72 hours after application. However, the grass recovered in about 2 weeks. (photo credit: C. A. Wilen, UC)

However, in some cases, especially where annual weeds are small, these products may be appropriate. These herbicides are best used on small weeds and annual weeds or for controlling weeds in cracks and, in some cases, edging. They can be used for spot spraying, but care must be taken that the spray or drift doesn't contact desirable plants or else leaf spotting or death will occur.

Increasing the Odds

Ways to improve efficacy when using these types of herbicides include:

  • Good spray coverage;
  • Application in warm weather (75° to 80°F);
  • If using concentrates, addition of surfactants that improve weed control;
  • Treatment when weeds are small; and
  • Repeat applications for larger weeds, in most instances.

Corn Gluten Meal

Another common natural herbicide is corn gluten meal (CGM). While the previously listed herbicides are postemergent types, CGM is sold as preemergent herbicide. Although being widely touted as an effective herbicide that will control seedlings as they geminate, we have conducted numerous tests with this product and haven't been able to get results that justify its use as an effective preemergent herbicide. For example, there were no differences in the time needed to remove weeds from plots treated with CGM than from plants that were handweeded or from plots that were not subjected to any other treatment (Figure 2).

Figure 2. Time needed to weed a landscape beds that were treated with the shown materials.
Figure 2. Time needed to weed a landscape beds that were treated with the shown materials.


So the question is: Are natural herbicides safe and effective? If used as part of an integrated pest management program, the contact herbicides fit very well. Users should know that they won't get the same kind of long-term weed control as products containing glyphosate (e.g., Roundup). The user should also be aware that many of the plant based or “natural” products can cause skin irritation or eye or lung problems. Eye protection and gloves as well as any other label requirements should be worn when using these natural herbicides, even if they are listed as exempt products. Note that some of the acetic acid products can be quite hazardous to handle.

Trade Names

Examples of plant essential oil-based herbicides include WeedZap, Bioganic Broadleaf Killer, and EcoSmart Weed and Grass Killer.

Examples of orange oil (d-limonene) based herbicides include Avenger and Worry Free Weed and Grass Killer.

Examples of acetic acid-based herbicides include WeedPharm (Signal word: Danger), AllDown, and Grotek Elimaweed Weed and Grass Killer. Note: The acetic acid concentration for herbicidal use should be about 10 to 20%. Household (food-use) vinegar is about 5% acetic acid and isn't effective for controlling most weeds.

Examples of fatty acid-based herbicides include Scythe, Safer Moss and Algae Killer, Safer Fast Acting Weed and Grass Killer, Monterey Herbicidal Soap, and Natria Weed and Grass Killer.

Combination products include Burn-out II (clove oil plus citric acid) and Earthtone 4n1 Weed Control RTU (soap of fatty acids plus maleic hydrazide, a growth regulator).

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